Basic Chemistry

  • All Matter in universe is composed of Atoms
    • Elements are composed of only 1 type of atom.
    • Atoms are mostly empty space.
    • Atoms have Electrons which are very small and are negatively charged and have a negligible mass (mass = 0).
    • Electrons move in orbits around the center of the atom - in relatively distinct areas called Energy Levels.(aka. Orbits or shells)
      • The farther from the center an electron is the more energy it has.
      • Electrons (& therefor atoms, can gain and lose energy) and do this by moving between energy levels.
    • Atoms have a Nucleus which contain Protons & Neutrons.
      • Protons are Positively Charged and have a mass =1
      • The number of protons in an atom’s nucleus determines what element it is
      • Neutrons have no charge and are therefor called Neutral and have a mass = 1.

The "basic" Atom

Summary of Subatomic Particles:
Particle
Location
Charge
Mass
PROTON
Nucleus
+1
1
NEUTRON
Nucleus
None / Neutral
1
ELECTRON
Energy Levels / orbits
-1
~0

Periodic Table Notation:
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  • Chemical elements are represented on the periodic table using the above format.
    • The letter is an abbreviation of Element Name
    • Atomic Number is the number is the number of protons the atom has. It is the number of protons an element has which determines what element it is.
    • Mass number is the total mass of an atom in AMU. It is the same as the number of protons & neutrons of the element. One can calculate the number of neutrons an atom has by subtracting the atomic number (# protons) from the mass number. Mass number CAN change without changing the identity of the element.
      • Atoms having the same atomic numbers and different mass numbers are called Isotopes.


Isotopes:
  • Isotopes are atoms of the same element with different numbers of neutrons (mass).
    • They react chemically the same as the "normal" form of the element
    • They are frequently radioactive
Example Isotopes: Hydrogen
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Interactions of matter:
  • Atoms interact through the process of chemical bonding.
    • Process is determined by the number of electrons found in the outermost energy level of an atom.
    • Involves the transfer & sharing of electrons between atoms.
  • ELECTRON / ENERGY LEVEL RULES:
    • Atoms in a neutral state have an equal number of protons and electrons.
    • Atoms "fill up" their energy levels from the lowest to the highest. Electrons rarely "skip" levels.
    • The 1st Energy level can only hold 2 electrons
    • The 2nd and 3rd energy levels can only hold 8 electrons
    • Atoms seek to have a "full" outermost energy level. All chemical reactions happen to accomplish this
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Chemical Bonds
  • When a Chemical Reaction occurs atoms gain, lose or share electrons.
    • Atoms always want to have their outer energy level "full" of electrons
    • When an atom has a different number of protons & electrons it is called an Ion.
      • If an ion has more protons than electrons - it is Positively Charged
      • If an atom has more electrons than protons it is Negatively Charged.
      • Atoms of opposite charge are attracted to each other.
  • There are three types of chemical bonds. Ionic bonds, Covalent Bonds, & Metallic Bonds.
    • Ionic bonds form when 1 atom "gives" one or more electrons to another atom.
      • This results in 1 positively charged ion & 1 negatively charged ion
      • Since opposite charges attract, they come together and bond
    • Covalent bonds form when 2 atoms "share" one or more electrons between them.
    • There are 2 types of covalent bonds:
      • Non-Polar Covalent bonds form when two atoms share electrons equally
      • Polar Covalent bonds form when two atoms share electrons unequally.
      • Atoms can share more than 1 electron between them forming multiple bonds
    • A Molecule is a group of 2 or more atoms held together by covalent bonds.
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Ionic Bonding

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Covalent Bonding
Summary of Ionic & Covalent Bonds

Chemical Reactions
  • A Chemical Reaction = whenever a chemical bond is formed or broken.
    • 2 types (sometimes 3) of substances with chemical reactants
      • Reactants = Substances existing before the reaction
      • Products = Substances existing after the reaction
      • Catalysts = Substances which speed up the rate of a reaction
    • Chemical Equations are a shorthand way of showing chemical reactions.
      • Separates Products and reactants.
      • Usually follow flow of energy.
        • Rx’s naturally occur when they release energy
        • Can however occur when energy is added.
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Structural Formulas:
  • Structural Formulas are used to graphically represent a chemical formula
    • Useful in visualizing how chemicals react and form new ones.
    • When drawing them use the following rules:
      • The Periodic table abbreviation is used to represent the atoms.
      • A single strait line (---) represents a single bond
      • Two parallel strait lines (==) represent double bonds
      • Examples:
Chemical Name
Chemical Formula
Structural Formula
Water
H2O
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